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New In-Pd mechanical loss peak in ternary gold alloys

Identifieur interne : 000846 ( Main/Repository ); précédent : 000845; suivant : 000847

New In-Pd mechanical loss peak in ternary gold alloys

Auteurs : RBID : Pascal:13-0322334

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Abstract

A point defect relaxation peak has been observed in a ternary 18-carat gold alloy with the composition Au62.5Pd32.5In5. It shows a Curie-Weiss dependence on the temperature, as is commonly observed for a Zener peak. However, the peak is absent in the binary alloys AuPd and AuIn and therefore it is a new type of relaxation that is due to In-Pd pairs. The relaxation strength shows a linear dependence on the indium concentration. We have developed a model of elastic dipoles containing one palladium and one indium atom in a gold matrix. The model is based on the reorientation under stress of InPd dipoles in a gold matrix and takes into account the atom ordering. The model accounts for a linear dependence of the relaxation strength on the indium concentration in a dilute alloy and is also valid for more concentrated alloys.

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Pascal:13-0322334

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<div type="abstract" xml:lang="en">A point defect relaxation peak has been observed in a ternary 18-carat gold alloy with the composition Au
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<sub>62.5</sub>
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<sub>32.5</sub>
In
<sub>5</sub>
. It shows a Curie-Weiss dependence on the temperature, as is commonly observed for a Zener peak. However, the peak is absent in the binary alloys AuPd and AuIn and therefore it is a new type of relaxation that is due to In-Pd pairs. The relaxation strength shows a linear dependence on the indium concentration. We have developed a model of elastic dipoles containing one palladium and one indium atom in a gold matrix. The model is based on the reorientation under stress of InPd dipoles in a gold matrix and takes into account the atom ordering. The model accounts for a linear dependence of the relaxation strength on the indium concentration in a dilute alloy and is also valid for more concentrated alloys.</s0>
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