New In-Pd mechanical loss peak in ternary gold alloys
Identifieur interne : 000846 ( Main/Repository ); précédent : 000845; suivant : 000847New In-Pd mechanical loss peak in ternary gold alloys
Auteurs : RBID : Pascal:13-0322334Descripteurs français
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Abstract
A point defect relaxation peak has been observed in a ternary 18-carat gold alloy with the composition Au62.5Pd32.5In5. It shows a Curie-Weiss dependence on the temperature, as is commonly observed for a Zener peak. However, the peak is absent in the binary alloys AuPd and AuIn and therefore it is a new type of relaxation that is due to In-Pd pairs. The relaxation strength shows a linear dependence on the indium concentration. We have developed a model of elastic dipoles containing one palladium and one indium atom in a gold matrix. The model is based on the reorientation under stress of InPd dipoles in a gold matrix and takes into account the atom ordering. The model accounts for a linear dependence of the relaxation strength on the indium concentration in a dilute alloy and is also valid for more concentrated alloys.
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<author><name sortKey="Maier, Ann Kathrin" uniqKey="Maier A">Ann-Kathrin Maier</name>
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<author><name sortKey="Tkalcec, Iva" uniqKey="Tkalcec I">Iva Tkalcec</name>
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<author><name sortKey="Mari, Daniele" uniqKey="Mari D">Daniele Mari</name>
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<author><name sortKey="Schaller, Robert" uniqKey="Schaller R">Robert Schaller</name>
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<keywords scheme="Pascal" xml:lang="fr"><term>Alliage ternaire</term>
<term>Défaut ponctuel</term>
<term>Frottement interne</term>
<term>Solution solide</term>
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<front><div type="abstract" xml:lang="en">A point defect relaxation peak has been observed in a ternary 18-carat gold alloy with the composition Au<sub>62.5</sub>
Pd<sub>32.5</sub>
In<sub>5</sub>
. It shows a Curie-Weiss dependence on the temperature, as is commonly observed for a Zener peak. However, the peak is absent in the binary alloys AuPd and AuIn and therefore it is a new type of relaxation that is due to In-Pd pairs. The relaxation strength shows a linear dependence on the indium concentration. We have developed a model of elastic dipoles containing one palladium and one indium atom in a gold matrix. The model is based on the reorientation under stress of InPd dipoles in a gold matrix and takes into account the atom ordering. The model accounts for a linear dependence of the relaxation strength on the indium concentration in a dilute alloy and is also valid for more concentrated alloys.</div>
</front>
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<fA08 i1="01" i2="1" l="ENG"><s1>New In-Pd mechanical loss peak in ternary gold alloys</s1>
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<fA11 i1="01" i2="1"><s1>MAIER (Ann-Kathrin)</s1>
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<fA11 i1="02" i2="1"><s1>TKALCEC (Iva)</s1>
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<fA11 i1="03" i2="1"><s1>MARI (Daniele)</s1>
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<fA11 i1="04" i2="1"><s1>SCHALLER (Robert)</s1>
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<fA14 i1="01"><s1>Ecole Polytechnique Fédérale de Lausanne, Institute of Condensed Matter Physics, Station 3</s1>
<s2>1015 Lausanne</s2>
<s3>CHE</s3>
<sZ>1 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>A point defect relaxation peak has been observed in a ternary 18-carat gold alloy with the composition Au<sub>62.5</sub>
Pd<sub>32.5</sub>
In<sub>5</sub>
. It shows a Curie-Weiss dependence on the temperature, as is commonly observed for a Zener peak. However, the peak is absent in the binary alloys AuPd and AuIn and therefore it is a new type of relaxation that is due to In-Pd pairs. The relaxation strength shows a linear dependence on the indium concentration. We have developed a model of elastic dipoles containing one palladium and one indium atom in a gold matrix. The model is based on the reorientation under stress of InPd dipoles in a gold matrix and takes into account the atom ordering. The model accounts for a linear dependence of the relaxation strength on the indium concentration in a dilute alloy and is also valid for more concentrated alloys.</s0>
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<fC02 i1="01" i2="X"><s0>001D11A</s0>
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<fC02 i1="02" i2="X"><s0>240</s0>
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<fC03 i1="01" i2="X" l="FRE"><s0>Alliage ternaire</s0>
<s5>55</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Ternary alloy</s0>
<s5>55</s5>
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<fC03 i1="01" i2="X" l="SPA"><s0>Aleación ternaria</s0>
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<s5>56</s5>
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<s5>56</s5>
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<s5>56</s5>
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<s5>56</s5>
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<s5>57</s5>
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<s5>57</s5>
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<fC03 i1="03" i2="X" l="GER"><s0>Innere Reibung</s0>
<s5>57</s5>
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<fC03 i1="03" i2="X" l="SPA"><s0>Frotamiento interno</s0>
<s5>57</s5>
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<fC03 i1="04" i2="X" l="FRE"><s0>Solution solide</s0>
<s5>58</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Solid solution</s0>
<s5>58</s5>
</fC03>
<fC03 i1="04" i2="X" l="GER"><s0>Mischkristall</s0>
<s5>58</s5>
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<fC03 i1="04" i2="X" l="SPA"><s0>Solución sólida</s0>
<s5>58</s5>
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<fN21><s1>301</s1>
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<fN44 i1="01"><s1>OTO</s1>
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